View Full Version : Is Calcium Necessary?
bobrfish
06-14-2009, 11:41 PM
I have been checking this
calcium theory out.
I used a water hardness test kit from Tetra and have also compared
these results to those performed by company selling water softners.
Water hardness may and
will include divalent cations other than calcium. However, city test report indicates that calcium
represents greater than 95% of divalent ions in tap water.
Currently all water is passing
through a softner stripping hardness out of water. One recent check revealed 15-20 ppm hardness.
Reset water softner and water tested at zero ppm hardness. I presume that some calcium scale
remained in the tanks, the tanks were filled with water containing 350-400 ppm calcium prior to
change. Leaching of residue calcium from scale is possible and would vary from tank to tank. Even
so, calcium concentration must be low and dropping lower with each water change.
Substrate in
tanks is sand or red flint gravel (sand blasting gravel). Neither is known to leach calcium.
Cichlid adults from all areas - no effect
Breeding results thus far:
Lake
Malawi no effect
Lake Victoria no effect
Lake Tanganyika no effect on Julidochromis,
Neolamprologus, Cyprichromis
Central America no effect on Vieja, Hericthys, Amphilopus
South America no effect on Geophagus steindachneri
Fry raised did not suffer greater
mortality than fry raised prior to switch.
At some point I will switch some tanks back
to hard water. Probably Lake Tanganyika tanks with some species that have not bred yet.
DogFish
06-15-2009, 12:01 AM
Chemical Constituent of
the Rift Lakes
Total hardness as calcium carbonate CaCO3 (mg/L)
L. Victoria
19.12--70.83
L. Malawi 60.58--85.60
L. Tanganyika 186.33--
460.0
Mrfiremouth
06-15-2009, 10:12 AM
Bob,
not sure
what or where you are headed with this.
I usually boost Calcium in my fry tanks to help aid in
fry development.
I am unsure if there is a study showing any gains, but Jack Whatley wrote
once in an old article that he saw no problem with people raising Discus fry in Hard water with
higher levels of Calcium and that he thought it would benefit the growth rate of these fry.(It was
in his TFH series, but I can not remember which one).
I read this about mid 90's and
have always boosted water hardness for fry since. Not sure if it has positive or negative impact as
my fry loss is usually do to me not feeding the fry tanks enough during that crucial first 3 weeks
of life.
bobrfish
06-15-2009, 3:00 PM
I do not see a problem
with raising fry in hard water tanks either.
Is there evidence that calcium concentration in
water is coorelated with fry health and growth or is it supposition?
DogFish
06-15-2009, 3:42 PM
Do you have a conductivity
to measure the water coming in to the house before it goes through the softer. Then the water after
it goes through softer?
Have you checked your Alkalinity?
Something I've
learned is that L. Victoria and L. Malawi, the water is not as hard as I thought it was.
Only
L. Tanganyika would be consider a hard water lake.
bobrfish
06-15-2009, 6:22 PM
I do not have a conductivity
meter.
Alkalinity or carbonate is unchanged, it remains at 350 ppm
DogFish
06-16-2009, 2:14 PM
When you start adding or
taking away chemicals in the water. Ionic imbalance occurs when Chloride and or sodium become
major anions. The reason I asked about a conductivity meter was so I could work out your Osmotic
Pressure.
Freshwater fish need to maintain a higher level of salt then the water there
in. If it gets out of balance it can cause the fish to be stressed out.
I'm learning
about this myself. if you get the ionic and osmotic difference between the the fish and the
aquarium water it can cause undue stress on the gills.
bobrfish
06-16-2009, 2:24 PM
At what ionic concentration
and osmotic pressure are freshwater fish gills under undue stress?
DogFish
06-16-2009, 3:56 PM
I"ll work out L.
Victoria.
Electrical Conductivity-----91-145 microsiemens for this example I'll use
the figure of 120 microsiemens.
The next thing is to take conductivity to Total
dissolved solids, a little math.
To get from conductivity to TDS you need a conversion
number for the City of Tampa the water dept gives it at .61 every water dept has a number.
For L. Victoria I know the TDS ranges 58.24--118.0 to get my conversion number I divided 91 by
58.24 and rounded it off .63 which is my conversion number for L. Victoria.
120 x .63 =
75.60 ppm which is my TDS number.
take that number divided it by 100
75.60divided by 100 = 7.56 lbs per square inch . Lake Victoria has a osmotic pressure around
7.56
with these formulas you can use on you own aquarium.
Total
Hardness; Calcium, Magnesium, Alkalinity (Calcium Carbonate) and so on. There have conversion
factors also.
You can take The approximate TDS subtracting the total ions from it.
To answer your question Is calcium necessary, I would think that it helps with the ionic
balance which osmoregulation relys on.
bobrfish
06-16-2009, 5:31 PM
I missed something in the
last post. What is the number at which undue stress to gills occurs?
Sodium has
replaced calcium in water via water softner, thus ionic strength remains the same and osmotic
pressure is actually higher in this water.
That is because osmotic pressure is based on
particle in solution. Take out one calcium particle and replace with two sodium particles. Thus
osmotic pressure is increased.
Ionic strength remains the same. as one calcium ion has plus 2
charge and it is replaced by two sodium ions each with a plus one charge.
DogFish
06-16-2009, 7:50 PM
The idea is to keep the
water in aquarium in the range of the fishes native habit.
OSMOTIC PRESSURE
Is the hydrostatic pressure produced by a difference in concentration between solutions on the
two sides of a surface ( a gill cell ). The cell of a fish gill and the surrounding water.
Ions that were in balance in the natural water (tap water or water source) are completely
out of balance.
I assume your water softer uses salt replacing the calcium. So by
replacing the calcium with sodium you are now making Chloride and or sodium the major cations or
anions in the water.
bobrfish
06-16-2009, 9:22 PM
It is true that calcium is
out and sodium is in when using a water softener. Chloride is not added to softened water,
chloride is lost down the drain when sodium binds to anion resin in water softner tank.
As far
as natural water goes. It would be amazing if the ionic composition and osmotic composition found
in water from the city of Apple Valley matched that of SA, CA, Lake Victoria, Lake Malawi, Lake
Tanganyika or any other natural water from which cichlids are taken.
My question
remains, at what osmotic gradient or ionic strength does undue stress on gills occur?
DogFish
06-16-2009, 9:38 PM
A lot of this is new to me
and I"m doing a lousy job explaining it. Give me some time to think about your question and
I'll get back to you.
Mrfiremouth
06-17-2009, 12:49 AM
Bob, been doing some
searches on softeners....
<a href="http://www.angelfish.net/VBulletin/showpost.php?
p=84826&postcount=18"
target="_blank">http://www.angelfish.net/VBulletin/showpos...mp;postcount=18</a>
http://www.angelfish.net/VBulletin/showpos...mp;postcount=35 (http://www.angelfish.net/VBulletin/showpost.php?p=88982&postcount=35)
http://www.angelsplus.com/ArticleOsmosis.htm
bobrfish
06-17-2009, 7:15 AM
Rich,
The first
article is wrong regarding osmotic pressure. It does not remain constant, but increases as 2
particles replace 1 particle. This is a bit easier for fish as increasing osmotic pressure allows
fish to use less energy to maintain particles in tissues and blood stream. Also, it is always
confusing to discuss particles that create osmotic pressure with ions and ionic strength. That is
not all particles that create osmotic pressure need to be ions but most are in fact ions.
All the articles imply or state sodium is harmful but calcium is not. My expierence suggests
these statements lack evidence to that claim.
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